Polymer Science and Materials Engineering Experiment

Author: Liu Jianping Zheng Yubin
Publisher:
Publish Date: 2005-04-01
Features: This book is mainly divided into five chapters. Chapter 1 mainly includes basic and commonly used polymerization experiments in polymer chemistry; Chapter 2 focuses on polymer characterization and performance analysis experiments in polymer physics, mainly covering the determination of polymer molecular weight, melt flow properties, crystallinity, and the identification of polymer functional groups; Chapter 3 covers the forming and processing of polymer materials, including formulation design, injection molding, extrusion molding, blow molding, leather coating, mold pressing, secondary processing, rubber processing technology, and composite material processing technology; Chapter 4 focuses on performance testing experiments of polymer materials, mainly including mechanical, electrical, and thermal properties of polymer materials; Chapter 5 is a comprehensive and design-oriented experiment, designed to train students' comprehensive experimental skills and independent experimental design capabilities. It mainly involves polymer chemistry experiments, polymer physics experiments, polymer material processing and modification, and polymer material testing. Through studying this part, students can achieve the goals of comprehensive and independent experiments. At the end of the book, an appendix is provided, which gives some basic data commonly used in experiments. This book is suitable for teaching use in polymer materials and related disciplines, and can also be used as a reference for researchers and engineering technicians engaged in polymer material research, development, and application.
Table of Contents
Table of Contents
Chapter 1 Basic Polymerization Experiments
Experiment 1 Styrene Solution Polymerization
Experiment 2 Styrene Emulsion Polymerization
Experiment 3 Styrene Suspension Polymerization
Experiment 4 Styrene Cationic Polymerization
Experiment 5 Determination of Styrene Radical Polymerization Reaction Rate by Dilatometry
Experiment 6 Preparation of Acrylonitrile-Butadiene-Styrene (ABS) Resin
Experiment 7 Preparation of Phenolic Resin by Acid Method
Experiment 8 Preparation of Phenolic Resin by Alkali Method
Experiment 9 Preparation of Epoxy Resin
Experiment 10 Bulk Polymerization of Methyl Methacrylate and Preparation of Acrylic Glass Plate
Experiment 11 Preparation of Unsaturated Polyester Resin and Glass Fiber Reinforced Plastic (GFRP)
Experiment 12 Preparation of Thermoplastic Polyurethane Elastomers
Experiment 13 Synthesis of Polyurethane Foam Plastics
Experiment 14 Preparation of Nylon-66 and Nylon-6
Experiment 15 Emulsion Copolymerization of Acrylonitrile and Vinyl Acetate
Chapter 2 Polymer Characterization and Performance Analysis Experiments
Experiment 16 Determination of Polymer Molecular Weight by End-Group Analysis
Experiment 17 Determination of Molecular Weight by Light Scattering
Experiment 18 Determination of Polymer Molecular Weight by Viscosity Method
Experiment 19 Determination of Molecular Weight by Vapor Pressure Osmometry
Experiment 20 Determination of Molecular Weight by Osmometry
Experiment 21 Gel Permeation Chromatography for Polymer Molecular Weight
Experiment 22 Determination of Glass Transition Temperature by Dilatometry
Experiment 23 Determination of Polymer Melt Flow Index
Experiment 24 Determination of Polymer Melt Flow Curve by Capillary Method
Experiment 25 Differential Thermal Analysis
Experiment 26 Thermogravimetric Analysis
Experiment 27 Determination of Polymer Density and Crystallinity by Density Gradient Tube Method
Experiment 28 Determination of Polyethylene Crystallinity by Reversed Gas Chromatography
Experiment 29 Transmission Electron Microscopy Observation of Polymer Spherulite Initial State
Experiment 30 Observation of Polymer Morphology by Scanning Electron Microscopy
Experiment 31 Infrared Spectroscopy for Polymer Identification
Chapter 3 Forming and Processing of Polymer Materials
Experiment 32 Injection Molding of Thermoplastic Plastics
Experiment 33 Extrusion and Pelletizing of Thermoplastic Plastics
Experiment 34 Extrusion Molding of Polyvinyl Chloride (PVC) Plastic Tubing
Experiment 35 Conical Twin-Screw Extrusion Molding of Rigid PVC Profiles
Experiment 36 Plastic Extrusion and Blow Film Molding
Experiment 37 Blow Molding of Hollow Plastic Products
Experiment 38 Preparation of Polyethylene Foam Materials
Experiment 39 Processing of Polyurethane Foam Plastics
Experiment 40 Indirect Coating of Artificial Leather Samples by Release Paper Method
Experiment 41 Hand-Laid Molding of Glass Fiber Reinforced Plastic (GFRP) Products
Experiment 42 Thickening of Unsaturated Polyester and Preparation of SMC
Experiment 43 SMC Laminating
Experiment 44 Preparation of Short-Fiber Premix for SMC
Experiment 45 Molding of GFRP Products
Experiment 46 Molding of Phenolic Plastics
Experiment 47 Preparation of Urea-Formaldehyde Resin and its Laminates
Experiment 48 Preparation of Melamine-Formaldehyde Resin and its Laminates
Experiment 49 Winding Molding of PVC/GFRP and PP/GFRP Composite Pipes
Experiment 50 Pull-Extrusion Molding of Composites
Experiment 51 Thermal Forming of Plastics
Experiment 52 Thermal Bonding of Plastic Films
Experiment 53 Welding of Plastics
Experiment 54 Bonding of Plastics
Experiment 55 Rubber Processing and Molding
Chapter 4 Performance Testing of Polymer Materials
Experiment 56 Mooney Viscosity Test
Experiment 57 Rubber Vulcanization Characteristics Test
Experiment 58 Rotational Rheometer Test
Experiment 59 Thermal Stability Test of Polyvinyl Chloride
Experiment 60 Determination of Polymer Vicat Softening Point
Experiment 61
Experiment 62 Thermal Aging Test of Plastics
Experiment 63 Oxygen Index Method for Determining Polymer Flammability
Experiment 64 Dynamic (Thermal) Mechanical Analysis of Polymer Materials
Experiment 65 Determination of Plastic Tensile Strength
Experiment 66 Determination of Plastic Impact Strength
Experiment 67 Determination of Dielectric Constant and Dielectric Loss
Experiment 68 Determination of Polymer Resistivity
Experiment 69 Determination of Plastic Hardness
Experiment 70 Testing of Transparency and Haze of Transparent Plastics
Chapter 5 Comprehensive and Design-Oriented Experiments
Experiment 71 Comprehensive Experiment of Methyl Methacrylate Polymerization
(1) Purification of Methyl Methacrylate
(2) Purification of Benzoyl Peroxide
(3) Bulk Polymerization of Methyl Methacrylate and Preparation of Acrylic Glass Plate
(4) Determination of Poly(methyl methacrylate) Molecular Weight by Viscosity Method
Experiment 72 Comprehensive Experiment of Styrene Polymerization
(1) Purification of Styrene
(2) Preparation of n-Butyllithium
(3) Anionic Polymerization of Styrene
(4) Purification of Polymers
(5) Determination of Polystyrene Molecular Weight and Distribution
Experiment 73 Comprehensive Experiment of Plastic Sample Processing and Mechanical Properties
(1) Preparation of Plastic Sheets by Twin-Roll Mill
(2) Molding of Plastic Boards
(3) Preparation of Tensile and Impact Test Specimens
(4) Tensile Strength Test of Specimens
(5) Impact Strength Test of Specimens
Experiment 74 Synthesis, Molecular Weight, and Distribution Determination of Narrow Molecular Weight Distribution Polystyrene
Experimental Design
(1) Synthesis Experiment Design of Narrow Molecular Weight Distribution Polystyrene
(2) Molecular Weight and Distribution Determination Experiment Design
Experiment 75 Styrene-Butadiene Copolymerization Experiment Design
Experiment 76 Acrylic Copolyester Experiment Design
Experiment 77 Filler Modification Experiment Design of Plastics
Experiment 78 Flame Retardancy Enhancement Experiment Design of Plastics
Experiment 79 Flame Retardancy and Flowability Enhancement Experiment Design of ABS
Appendix
Appendix 1 Purification of Common Monomers
Appendix 2 Purification of Initiators
Appendix 3 Determination of Acid Value
Appendix 4 Determination of Hydroxyl Value
Appendix 5 Determination of Epoxy Value
Appendix 6 Determination of Acrylonitrile Content
Appendix 7 Density Determination of Solids and Liquids by Density Bottle Method
Appendix 8 English Abbreviations of Common Polymers
Appendix 9 Physical Constants of Common Monomers
Appendix 10 Decomposition Rate Constants, Activity, and Half-Life of Common Initiators
Appendix 11 Chain Transfer Constants of Several Initiators (CI)
Appendix 12 Chain Transfer Constants of Several Solvents (or Modifiers) (60°C)
Appendix 13 Chain Transfer Constants of Monomers in Homopolymerization (CM)
Appendix 14 Competitive Reactivity of Monomers in Radical Copolymerization
Appendix 15 Competitive Reactivity of Some Monomers in Cationic Copolymerization
Appendix 16 Solvents and Precipitants (Non-Solvents) for Some Polymers
Appendix 17 Specific Viscosity-Molecular Weight Relationships of Some Polymers [η] = KMα
Appendix 18 θ Solvents for Some Polymers
Appendix 19 Densities of Some Common Polymers
Appendix 20 Crystallization Parameters of Some Representative Polymers
Appendix 21 Glass Transition Temperatures (Tg) and Melting Points (Tm) of Some Polymers
Appendix 22 Refractive Indices of Some Polymers
References