Electrolyte solution theory

Author: Li Yigui Lu Jiufang
Publisher:
Publish Date: 2005-03-01
Features: This book systematically introduces the theory of electrolyte solutions and its latest advancements based on a review of classical thermodynamics, statistical mechanics, and molecular mechanics. It elaborates on classical electrolyte solution theories (Debye-Huckel theory, ion hydration theory, ion association theory, Pitzer theory, and local composition models). Starting from molecular microscopic parameters and molecular interactions, it discusses molecular simulation methods, integral equation theory (distribution function theory), perturbation theory, and modern critical theories that have developed over the past decade, as well as their applications in phase equilibrium calculations. To address the heterogeneity of electrolyte solutions, the book also introduces interface theory and charged colloid solution theory for electrolyte solutions. Additionally, it discusses conductivity theory and diffusion theory in relation to the transport properties of electrolytes. The book is divided into 15 chapters. Considering that some chapters involve complex mathematical derivations, three mathematical appendices are included. This book will help promote the development of theoretical and applied research on electrolyte solutions in China and is suitable for researchers engaged in electrolyte solution theory, university faculty and students, as well as scientists and engineers in fields such as inorganic chemical engineering, salt lake development, natural gas chemical engineering, environmental chemical engineering, biochemical engineering, and hydrometallurgy for modeling and process optimization.